The following is the list of principals from foundation till date:

1. Late Rev. Fr. John J. Keaveney – Jan 1951 – Dec 1953
2. Late Rev. Fr. Francis Mac Govern – Jan 1954 – Dec 1956
3. Late Rev. Fr. (Dr) Peter Kelly – Jan 1957 – Dec 1959
4. Late Rev. Fr. Michael O’Shea – Jan 1960 – Apr 1967
5. Late Rev. Fr. Michael M. Evans – 1967 – 1976
6. Chief Ade Iluyemi – 1976 – 1977
7. Elder Enoch Dare – 1977 – 1986
8. Late Chief Sir Michael Ibikunle – 1986 – 1987 (Aquinarian)
9. Late Chief Emmanuel R. A. Babalola – 1988 – Apr 2001 (Aquinarian)
10. Late Mr. Joseph A. Ogundolie – May 2001 – 2006
11. Late Chief M. A. Fasuyi (Principal SSS) – 2006 – 2011
12. Mr. Ojo T. Ale ( Principal JSS) – 2006 – 2011
13. Mr. J. O. Alo – 2011 – 2013
14. Pastor Babasola Ayibiowu – 2013 – Nov 2019 (Aquinarian)
15. Mr. Olusola J. Adeyeye – Nov 2019 – May 2020 (Aquinarian)
16. Joseph A. Ige (Acting Principal) – May 2020 – Nov 2020
17. Afolabi Oni. Nov 2020 – Date (Aquinarian)